Study of Physical and Optical Properties of Cobalt Oxide Doped Glass Prepared by Microwave Melting Technique

Authors

  • Pattraporn Saengka Nakhon Pathom Rajabhat University
  • Nakarin Singkiburin Nakhon Pathom Rajabhat University
  • Keerati Kirdsiri Nakhon Pathom Rajabhat University
  • Nattapon Srisittipokakun Nakhon Pathom Rajabhat University

DOI:

https://doi.org/10.53848/ssstj.v12i1.1033

Keywords:

Microwave melting technique, CoO, Glass, Physical and Optical properties

Abstract

This research investigates the physical and optical properties of cobalt oxide-doped glass prepared using the microwave melting technique. The glass composition was formulated according to the ratio (50-x)B2O3 : 10SiO2 : 30ZnO : 10Na2O : xCoO, where x represents the cobalt oxide concentration (0.00, 0.01, 0.05, 0.10, 0.15, and 0.20 mol%). Glass samples were prepared using the microwave melting technique, applying 1,000 watts of power for 20 minutes. The melted glass was then poured into a graphite mold and annealed at 500°C. The results showed that both density and refractive index increased with rising CoO concentration, while molar volume decreased. The absorption spectra of the glass, in the wavelength range of 250-1,100 nm, increased with higher CoO concentrations. Additionally, the CIE L*a*b* values indicated a blue color.

References

Ali, A.A, Rammah, Y.S, El-Mallawany, R. & Souri, D. (2017). FTIR and UV spectra of pentaternary borate glasses data set. University of

Measurement, 105, 72–77. doi: org/10.1016/j.measurement.2017.04.010.

Al-Mokhtar, K. M. (2020). FTIR and optical absorption studies of [B2O3]-[Na2O]-[Li2O]-[CuO] doped with [MgF2] nanoparticle. Journal of Nanotechnology & Advanced Materials, 8(2), 45-51.

Bolundut. Liviu, Pascuta. Petru, Culea. Eugen, Bos. Maria, Pop, Lidia & Stefan. Razvan, (2020). Spectroscopic study of some new cobalt-

doped tellurite glass–ceramics. Meterials Science, 55, 9962-9971. doi: org/10.1007/s10853-020-04749-6.

Elbashar, Y.H., Rayan, Diaa., ElGabaly, Shimaa G. & Mohamed, A.A., (2020). Optical Spectroscopic Study of Cobalt Oxide Doped Boron

Glass and Its Ion Effect on Optical Properties. Chemistry, 63, (6), 2111 – 2124. doi: 10.21608/ejchem.2019.17471.2072.

Farouk, M., (2017). Effect of Co2+ ions on the ligand field, optical, and structural properties of ZnLiB glasses.Optik, 140, 186–196.

doi: org/10.1016/j.ijleo.2017.04.042.

Fayad, A. M., Shaaban, Kh. S., Abd Allah, W. M., Ouis, M., (2020). Structural and Optical Study of CoO Doping in Borophosphate Host

Glass and Efect of Gamma Irradiation. Inorganic and Organometallic Polymers and Materials, 30, 5042–5052.

doi.org/10.1007/s10904-020-01641-3.

Naresh, P., Naga Raju, Gandhi, G.Y., Piasecki, M. & Veeraiah, N., (2014). Insulating and other physical properties

of CoO-doped zinc oxyfluoride-borate glass-ceramics, The American Ceramic Society, 98, (2), 413–422. doi: 10.1111/jace.13301.

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Published

2025-04-10

How to Cite

Saengka, P., Singkiburin, N. ., Kirdsiri, K. ., & Srisittipokakun, N. . (2025). Study of Physical and Optical Properties of Cobalt Oxide Doped Glass Prepared by Microwave Melting Technique. Suan Sunandha Science and Technology Journal, 12(1), 16–24. https://doi.org/10.53848/ssstj.v12i1.1033

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Section

Research Articles