The Preparation of Hybrid Material of Cobalt Complex into Mesoporous Silica from the Rice Husk
Keywords:
Hybrid material, Mesoporous silica, Bis(8-hydroxyquinoline)cobalt(II), Rice huskAbstract
A luminescence hybrid material, Bis(8-hydroxyquinoline)cobalt(II) (Co(8hq) 2), was incorporated into the mesoporous silica. To study the preparation of mesoporous silica from rice husk and the development of fluorescence efficiency. The mesoporous silica was prepared by swelling-shrinking mechanism which used the sodium silicate from rice husk as the precursor. The hybrid materials were prepared by solid-state reaction at room temperature with two different routes; the first one was the hybrid material processes via the in situ formation of cobalt(II)chloride hexahydrate (CoCl26H 2O) as well as 8hq into the mesoporous silica (MCM) mixed ground
(MCM_Co(8hq) 2) and the another one was step by step ground of the mesoporous silica, cobalt(II)chloride hexahydrate and 8hq (MCMCo(II)_8hq). The hybrid materials were characterized by SEM, XRD, FT-IR, AAS, as well as PL. The FT-IR spectra showed the 8hq characteristic at 820, 786, 784, and 747 cm-1 that all of the FT- IR spectra shifted to higher frequencies of free 8hq (815, 778, and 739 cm-1 ), confirming the coordination between cobalt(II) cation and 8-hydroxyquinoline. The excellent photoluminescence of MCM_Co(8hq) 2 revealed at 484 nm and MCMCo(II)_8hq demonstrated blue-shifted peak at 474 nm in this comparison, indicating that the formation of different nanostructures and/or packing of bis (8-hydroxyquinoline)cobalt(II) were formed into the mesoporous silica.
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